Horizon Call of the Mountain
This is a new entry in one of PlayStation's biggest modern franchises, and one that was built from the ground up for VR. The opening five minutes – a Jurassic Park-style boat ride that replaces real dinosaurs with the series' robotic equivalent – are simply breathtaking.
Whether you're scaling is an incredibly immersive 6-8hr romp that should absolutely be the first game you play on your new hardware.